CAS: | 128-37-0 | MF: | C15H24O |
---|---|---|---|
Product Name: | 2,6-Di-tert-butyl-4-methylphenol | EINECS: | 204-881-4 |
Density: | 0.927g/cm3 | Melting Point: | 69-71℃ |
Boiling Point: | 263.6°C At 760 MmHg | Flash Point: | 118.4°C |
High Light: | 128-37-0 Butylated Hydroxytoluene,C15H24O CAS128-37-0,C15H24O Butylated Hydroxytoluene |
128-37-0 C15H24O 263.6°C at 760 mmHg insoluble
Product name: 2,6-Di-tert-butyl-4-methylphenol
Industrial production
The chemical synthesis of BHT in industry has involved the reaction of p-cresol (4-methylphenol) with isobutylene (2-methylpropene), catalyzed by sulfuric acid:
CH3(C6H4)OH + 2 CH2=C(CH3)2 → ((CH3)3C)2CH3C6H2OH
Alternatively, BHT has been prepared from 2,6-di-tert-butylphenol by hydroxymethylation or aminomethylation followed by hydrogenolysis.
Reactions
The species behaves as a synthetic analog of vitamin E, primarily acting as a terminating agent that suppresses autoxidation, a process whereby unsaturated (usually) organic compounds are attacked by atmospheric oxygen. BHT stops this autocatalytic reaction by converting peroxy radicals to hydroperoxides. It effects this function by donating a hydrogen atom:
RO2• + ArOH → ROOH + ArO•
RO2• + ArO• → nonradical products
CAS RN: 128-37-0
EINECS No.: 204-881-4
Molecular formula: C15H24O
Molecular weight: 220.3505
InChI: InChI=1/C15H24O/c1-10-8-11(14(2,3)4)13(16)12(9-10)15(5,6)7/h8-9,16H,1-7H3
Density: 0.927g/cm3
Melting point: 69-71℃
Boiling point: 263.6°C at 760 mmHg
Flash point: 118.4°C
Solubility: insoluble
Vapor pressure: 0.00624mmHg at 25°C
Melting point | 69-73 °C(lit.) |
Boiling point | 265 °C(lit.) |
density | 1.048 |
vapor density | 7.6 (vs air) |
vapor pressure | <0.01 mm Hg ( 20 °C) |
FEMA | 2184 | BUTYLATED HYDROXYTOLUENE |
refractive index | 1.4859 |
Fp | 127 °C |
storage temp. | 0-6°C |
solubility | methanol: 0.1 g/mL, clear, colorless |
pka | pKa 14(H2O t = 25 c = 0.002 to 0.01) (Uncertain) |
form | Crystals |
color | white |
Odor | faint characteristic odor |
Water Solubility | insoluble |
Merck | 14,1548 |
BRN | 1911640 |
Stability: | Stable, but light-sensitive. Incompatible with acid chlorides, acid anhydrides, brass, copper, copper alloys, steel, bases, oxidizing agents. Combustible. |
InChIKey | NLZUEZXRPGMBCV-UHFFFAOYSA-N |
CAS DataBase Reference | 128-37-0(CAS DataBase Reference) |
IARC | 3 (Vol. 40, Sup 7) 1987 |
NIST Chemistry Reference | Butylated hydroxytoluene(128-37-0) |
EPA Substance Registry System | 2,6-Di-tert-butyl-p-cresol (128-37-0) |
Hazard Codes | Xn,N |
Risk Statements | 22-36/37/38-36/38-50/53 |
Safety Statements | 26-36-37/39-61-60 |
RIDADR | 3077 |
WGK Germany | 1 |
RTECS | GO7875000 |
F | 8-10-23 |
Autoignition Temperature | 878 °F |
TSCA | Yes |
HazardClass | 9 |
PackingGroup | III |
HS Code | 29071900 |
Hazardous Substances Data |
128-37-0(Hazardous Substances Data) |
Toxicity | LD50 orally in mice: 1040 mg/kg (McOmie) |
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